Autocatalytic Carbonyl Arylation through In Situ Release of Aryl Nucleophiles from N ‐Aryl‐ N ′‐Silyldiazenes
نویسندگان
چکیده
منابع مشابه
Direct N-arylation of purines with aryl halides†
Purine is a ubiquitous heterocyclic scaffold of fundamental importance, and is considered to be a privileged structure in medicinal chemistry. Purine-based compounds, including N-aryl purines, exhibit a wide range of biological and pharmaceutical activities, such as antiviral, antibacterial and anticancer effects. In light of their importance, there is a surprising paucity of efficient methods ...
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In this paper, quantum chemical parameters at density functional theory (DFT) B3LYP/6-31G** (d,p) level of theory were calculated for three organic corrosion inhibitors [N-benzoyl-N-(p-aminophenyl) thiourea, N-benzoyl-N-(thiazole) thiourea and N-acetyl-N-(dibenzyl) thiourea. The calculated molecular descriptors such as the HOMO, LUMO, dipole moment, chemical potential (μ), chemical hardness (ղ)...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2020
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.201916004